The r30 efi head has larger intake valves and ports. Some R30 heads were round port exhaust, the N47 and others were square, the E88. The chambers are modern on both of the R30 heads. Fuel injection manifolds bolt to the head a bit differently than carby manifolds.
On the C210's I think they use a later version of the E30 head in which the intake ports were notched and the manifold bolting face drilled and tapped for efi. You'll need to check your Skylines head for this.
Taking the R30 head off and bolting it to the L24 block in the Skyline may require that you notch the block because of the larger valve heads.
You can take out the L24 and bolt in the L24E engine into your Skyline.
Do you know the condition of the engine/injection setup you wish to drop in? Have you heard it running......at all? Your entire fuel system will need to be upgraded to EFI spec too. Do the injectors need a service, is the advance dashpot on the efi distributor working and on it goes. Remember this stuff is pretty old now.
It could work out cheaply as a straightford swap or it could become a real pain in the arse.
And then there is the electrical side......
You can do it.....or chuck in a twin Su setup. Your call.